The ascii table is only useful if you're editing files that are SBCS/DBCS. For SlickEdit, that's typically source code files (.cpp, .java, etc.). It's not intended to be useful for Unicode files (i.e. utf-8/Utf-16 -- XML files). It helps you know how characters <256 will display in your font and gives you hex and decimal values.
It's a record file that has no line endings. That way you can see what your font will display for 10 and 13 characters. You'll have to specify a record width of 66 to open this file. The GUI open dialog no longer has a record width option. From the SlickEdit command line, "e +66 asciitab" will do the trick.